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A chromium tricarbonyl complex featuring the 4,6-bis(diphenylphosphinomethyl)dibenzothiophene (PSP(Ph)) ligand

ABSTRACT: The new PSP pincer ligand 4,6-bis(diphenylphosphinomethyl)dibenzothiophene (PSP(Ph)) was prepared in 89 % yield. With this ligand, a solvothermal synthesis of a Cr complex of the type [Cr(κ(3)P,S,P-PSP)(CO)(3)] is described. The X-ray structure of this compound is presented. We demonstrate...

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Publicat a:Monatsh Chem
Autors principals: Mastalir, Matthias, Schweinzer, Clara, Weil, Matthias, Pittenauer, Ernst, Allmaier, Günter, Kirchner, Karl
Format: Artigo
Idioma:Inglês
Publicat: Springer Vienna 2016
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4899494/
https://ncbi.nlm.nih.gov/pubmed/27358501
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00706-016-1707-9
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