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A chromium tricarbonyl complex featuring the 4,6-bis(diphenylphosphinomethyl)dibenzothiophene (PSP(Ph)) ligand
ABSTRACT: The new PSP pincer ligand 4,6-bis(diphenylphosphinomethyl)dibenzothiophene (PSP(Ph)) was prepared in 89 % yield. With this ligand, a solvothermal synthesis of a Cr complex of the type [Cr(κ(3)P,S,P-PSP)(CO)(3)] is described. The X-ray structure of this compound is presented. We demonstrate...
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Publié dans: | Monatsh Chem |
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Auteurs principaux: | , , , , , |
Format: | Artigo |
Langue: | Inglês |
Publié: |
Springer Vienna
2016
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Sujets: | |
Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4899494/ https://ncbi.nlm.nih.gov/pubmed/27358501 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00706-016-1707-9 |
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