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Synthesis of Neurotrophic Seco-prezizaane Sesquiterpenes (1R,10S)-2-oxo-3,4-dehydroneomajucin, (2S)-hydroxy-3,4-dehydroneomajucin, and (−)-jiadifenin
An asymmetric approach to the synthesis of neurotrophic seco-prezizaane sesquiterpenes is described that is based on strategic application of a hydroxyl-directed metallacycle-mediated [2+2+2] annulation and an intramolecular radical cyclization cascade. Targets prepared are among the most potent mem...
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| Izdano u: | J Am Chem Soc |
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| Glavni autori: | , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2016
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4879688/ https://ncbi.nlm.nih.gov/pubmed/26785051 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b12694 |
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