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Total Synthesis and Characterization of 7-Hypoquinuclidonium Tetrafluoroborate and 7-Hypoquinuclidone BF(3) Complex

Derivatives of the fully twisted bicyclic amide 7-hypoquinuclidone are synthesized using a Schmidt-Aubé reaction. Their structures were unambiguously confirmed by X-ray diffraction analysis and extensive spectroscopic characterization. Furthermore, the stability and chemical reactivity of these anti...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Liniger, Marc, VanderVelde, David G., Takase, Michael K., Shahgholi, Mona, Stoltz, Brian M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4878439/
https://ncbi.nlm.nih.gov/pubmed/26713861
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b11750
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