Dioxo–Molybdenum(VI) Complexes with Ene–1,2–dithiolate Ligands: Synthesis, Spectroscopy, and Oxygen Atom Transfer Reactivity

New dioxo–molybdenum(VI) complexes, (Et(4)N)(Ph(4)P)[Mo(VI)O(2)(S(2)C(2)(CO(2)Me)(2))(bdt)] (2) and (Et(4)N)(Ph(4)P)[Mo(VI)O(2)(S(2)C(2)(CO(2)Me)(2))(bdtCl(2))] (4) (S(2)C(2)(CO(2)Me)(2) = 1,2–dicarbomethoxyethylene–1,2–ditholate, bdt = 1,2–benzenedithiolate, bdtCl(2) = 3,6–dichloro–1,2–benzenedithi...

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Dettagli Bibliografici
Pubblicato in:Inorg Chem
Autori principali: Sugimoto, Hideki, Tatemoto, Susumu, Suyama, Koichiro, Miyake, Hiroyuki, Itoh, Shinobu, Dong, Chao, Yang, Jing, Kirk, Martin L.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2009
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Article
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4872601/
https://ncbi.nlm.nih.gov/pubmed/19831360
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic901112s
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