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Chalcogenidobis(ene–1,2–dithiolate)molybdenum(IV) complexes (chalcogenide E = S, Se): Probing Mo≡E and ene–1,2–dithiolate substituent effects on geometric and electronic structure()
New square–pyramidal bis(ene–1,2–dithiolate)MoSe complexes, [Mo(IV)Se(L)(2)](2−), have been synthesised along with their terminal sulfido analogues, [Mo(IV)S(L)(2)](2−), using alkyl (L(C4H8)), phenyl (L(Ph)) and methyl carboxylate (L(COOMe)) substituted dithiolene ligands (L(R)). These complexes now...
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| Главные авторы: | , , , , , , , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2010
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3168557/ https://ncbi.nlm.nih.gov/pubmed/21165484 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c0dt00871k |
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