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Oxo-carboxylato-molybdenum(VI) complexes possessing dithiolene ligand related to the active site of type II class of DMSOR family of molybdoenzymes
Spectroscopic and kinetic studies indicate that oxo-carboxylato-molybdenum(VI) bis-dithiolene complexes, (Mo(VI)O(p-X-OBz)L(2)), have been generated at low temperature as active site structural models for the type II class of pyranopterin molybdenum DMSOR family enzymes. A DFT analysis of low energy...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3856207/ https://ncbi.nlm.nih.gov/pubmed/24029827 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3dt51485d |
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