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Enantioselective Alcohol C-H Functionalization for Polyketide Construction: Unlocking Redox-Economy and Site-Selectivity for Ideal Chemical Synthesis

The development and application of stereo- and site-selective catalytic methods that directly convert lower alcohols to higher alcohols are described. These processes merge the characteristics of transfer hydrogenation and carbonyl addition, exploiting alcohols and π-unsaturated reactants as redox p...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Feng, Jiajie, Kasun, Zachary A., Krische, Michael J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4871165/
https://ncbi.nlm.nih.gov/pubmed/27113543
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b02019
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