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Modular Terpenoid Construction via Catalytic Enantioselective Formation of All-Carbon Quaternary Centers: Total Synthesis of Oridamycin A, Triptoquinone B and C and Isoiresin
Total syntheses of oridamycin A, triptoquinones B and C and isoiresin are accomplished from a common intermediate prepared via iridium catalyzed alcohol C-H tert-(hydroxy)-prenylation; a byproduct-free process that forms an all-carbon quaternary stereocenter with excellent control of diastereo- and...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5096378/ https://ncbi.nlm.nih.gov/pubmed/27632643 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b08902 |
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