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Redox-Triggered C–C Coupling of Alcohols and Vinyl Epoxides: Diastereo- and Enantioselective Formation of All-Carbon Quaternary Centers via tert-(Hydroxy)-Prenylation
[Image: see text] Iridium catalyzed primary alcohol oxidation triggers reductive C–O bond cleavage of isoprene oxide to form aldehyde-allyliridium pairs that combine to form products of tert-(hydroxy)-prenylation, a motif found in >2000 terpenoid natural products. Curtin–Hammett effects are explo...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
American Chemical
Society
2014
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| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4090370/ https://ncbi.nlm.nih.gov/pubmed/24915473 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja504625m |
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