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Poly(thioester) by Organocatalytic Ring-Opening Polymerization
Organocatalysts typically used for the ring-opening polymerization (ROP) of cyclic ester monomers are applied to a thiolactone, ε-thiocaprolactone (tCL). In the absence of an H-bond donor, a nucleophilic polymerization mechanism is proposed. Despite the decreased ability of thioesters and thiols (ve...
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| Udgivet i: | Macromolecules |
|---|---|
| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4863702/ https://ncbi.nlm.nih.gov/pubmed/27182085 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.macromol.5b01463 |
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