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Controlled Organocatalytic Ring-Opening Polymerization of ε-Thionocaprolactone
For the first time, the controlled ring-opening polymerization (ROP) of ε-thionocaprolactone (tnCL) is conducted. The organocatalytic ROP of tnCL occurs without carbonyl scrambling, leading to homopoly(ε-thionocaprolactone) (PtnCL). The ROP by base catalysts alone is proposed to proceed via a nucleo...
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| Publicado no: | Macromolecules |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4862612/ https://ncbi.nlm.nih.gov/pubmed/27182087 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.macromol.6b00136 |
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