Rate Accelerated Organocatalytic Ring-Opening Polymerization of L-Lactide via the Application of a Bis(thiourea) H-bond Donating Cocatalyst

A cocatalyst system consisting of an alkylamine base and a bis(thiourea) featuring a linear alkane tether is shown to dramatically increase the rate of ring-opening polymerization (ROP) of L-lactide versus previously disclosed monothiourea H-bond donors. Rate acceleration occurs regardless of the id...

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Udgivet i:Macromolecules
Main Authors: Spink, Samuel S., Kazakov, Oleg I., Kiesewetter, Elizabeth T., Kiesewetter, Matthew K.
Format: Artigo
Sprog:Inglês
Udgivet: 2015
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4863465/
https://ncbi.nlm.nih.gov/pubmed/27182086
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.macromol.5b01320
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