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Copper(II)-Promoted Cyclization/Difunctionalization of Allenols and Allenylsulfonamides: Synthesis of Heterocycle-Functionalized Vinyl Carboxylate Esters

A unique method to affect intramolecular aminooxygenation and dioxygenation of allenols and allenylsulfonamides is described. These operationally simple reactions occur under neutral or basic conditions where copper(II) carboxylates serve as reaction promoter, oxidant, and carboxylate source. Modera...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: Casavant, Barbara J., Khoder, Zainab M., Berhane, Ilyas A., Chemler, Sherry R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4861087/
https://ncbi.nlm.nih.gov/pubmed/26624861
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.5b02833
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