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Copper(II)-Promoted Cyclization/Difunctionalization of Allenols and Allenylsulfonamides: Synthesis of Heterocycle-Functionalized Vinyl Carboxylate Esters

A unique method to affect intramolecular aminooxygenation and dioxygenation of allenols and allenylsulfonamides is described. These operationally simple reactions occur under neutral or basic conditions where copper(II) carboxylates serve as reaction promoter, oxidant, and carboxylate source. Modera...

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Bibliografske podrobnosti
izdano v:Org Lett
Main Authors: Casavant, Barbara J., Khoder, Zainab M., Berhane, Ilyas A., Chemler, Sherry R.
Format: Artigo
Jezik:Inglês
Izdano: 2015
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4861087/
https://ncbi.nlm.nih.gov/pubmed/26624861
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.5b02833
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