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Ph(i-PrO)SiH(2): An Exceptional Reductant for Metal-Catalyzed Hydrogen Atom Transfers
We report the discovery of an outstanding reductant for metal-catalyzed radical hydrofunctionalization reactions. Observations of unexpected silane solvolysis distributions in the HAT-initiated hydrogenation of alkenes reveal that phenylsilane is not the kinetically preferred reductant in many of th...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4858193/ https://ncbi.nlm.nih.gov/pubmed/26984323 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b02032 |
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