Lataa...
Ph(i-PrO)SiH(2): An Exceptional Reductant for Metal-Catalyzed Hydrogen Atom Transfers
We report the discovery of an outstanding reductant for metal-catalyzed radical hydrofunctionalization reactions. Observations of unexpected silane solvolysis distributions in the HAT-initiated hydrogenation of alkenes reveal that phenylsilane is not the kinetically preferred reductant in many of th...
Tallennettuna:
| Julkaisussa: | J Am Chem Soc |
|---|---|
| Päätekijät: | , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2016
|
| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4858193/ https://ncbi.nlm.nih.gov/pubmed/26984323 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b02032 |
| Tagit: |
Lisää tagi
Ei tageja, Lisää ensimmäinen tagi!
|