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Mechanism and Reactivity of Rh-Catalyzed Intermolecular [5+1] Cycloaddition of 3-Acyloxy-1,4-Enyne (ACE) and CO: A Computational Study

The first theoretical study on the mechanism of [RhCl(CO)(2)](2)-catalyzed [5 + 1] cycloadditions of 3-acyloxy-1,4-enyne (ACE) and CO has been performed using density functional theory (DFT) calculations. The effect of ester on reactivity of this reaction has been investigated. The computational res...

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Bibliografiske detaljer
Udgivet i:Chin Chem Lett
Main Authors: Ke, Xiao-Na, Schienebeck, Casi M., Zhou, Chen-Chen, Xu, Xiufang, Tang, Weiping
Format: Artigo
Sprog:Inglês
Udgivet: 2015
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4852877/
https://ncbi.nlm.nih.gov/pubmed/27152064
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.cclet.2015.03.016
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