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Mechanism and Reactivity of Rh-Catalyzed Intermolecular [5+1] Cycloaddition of 3-Acyloxy-1,4-Enyne (ACE) and CO: A Computational Study
The first theoretical study on the mechanism of [RhCl(CO)(2)](2)-catalyzed [5 + 1] cycloadditions of 3-acyloxy-1,4-enyne (ACE) and CO has been performed using density functional theory (DFT) calculations. The effect of ester on reactivity of this reaction has been investigated. The computational res...
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| Udgivet i: | Chin Chem Lett |
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| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4852877/ https://ncbi.nlm.nih.gov/pubmed/27152064 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.cclet.2015.03.016 |
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