A synthetic, catalytic and theoretical investigation of an unsymmetrical SCN pincer palladacycle

The SCN ligand 2-{3-[(methylsulfanyl)methyl]phenyl}pyridine, 1, has been synthesized starting from an initial Suzuki–Miyaura (SM) coupling between 3-((hydroxymethyl)phenyl)boronic acid and 2-bromopyridine. The C–H activation of 1 with in situ formed Pd(MeCN)(4)(BF(4))(2) has been studied and leads t...

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Vydáno v:R Soc Open Sci
Hlavní autoři: Roffe, Gavin W., Boonseng, Sarote, Baltus, Christine B., Coles, Simon J., Day, Iain J., Jones, Rhiannon N., Press, Neil J., Ruiz, Mario, Tizzard, Graham J., Cox, Hazel, Spencer, John
Médium: Artigo
Jazyk:Inglês
Vydáno: The Royal Society 2016
Témata:
Chemistry
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4852630/
https://ncbi.nlm.nih.gov/pubmed/27152207
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1098/rsos.150656
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