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Catalytic Asymmetric Mannich Reactions with Fluorinated Aromatic Ketones: Efficient Access to Chiral β-Fluoroamines
Herein, we report a Zn-Prophenol catalyzed Mannich reaction using fluorinated aromatic ketones as nucleophilic partners for the direct enantio- and diastereoselective construction of β–fluoroamine motifs featuring a fluorinated tetrasubstituted carbon. The reaction can be run on a gram-scale with a...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4837127/ https://ncbi.nlm.nih.gov/pubmed/26609784 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201509719 |
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