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Asymmetric Synthesis of Axinellamines A and B
Axinellamines A and B are broad-spectrum anti-bacterial pyrrole–imidazole alkaloids that have a complex polycyclic skeleton. A new asymmetric synthesis of these marine sponge metabolites is described herein, featuring an oxidative rearrangement and an anchimeric chlorination reaction.
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| 發表在: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2016
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4836294/ https://ncbi.nlm.nih.gov/pubmed/27037993 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201600007 |
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