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Asymmetric Synthesis of Ageliferin
We describe herein an asymmetric synthesis of ageliferin. A Mn(III)-mediated oxidative radical cyclization reaction was used as the key step to construct the core skeleton of this pyrrole-imidazole dimer. This approach resembles the bio-genic [4+2] dimerization in an intramolecular fashion.
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Main Authors: | , , , , |
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Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
2011
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3183238/ https://ncbi.nlm.nih.gov/pubmed/21888421 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja207386q |
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