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Asymmetric syntheses of sceptrin and massadine and evidence for biosynthetic enantiodivergence
Cycloaddition is an essential tool in chemical synthesis. Instead of using light or heat as a driving force, marine sponges promote cycloaddition with a more versatile but poorly understood mechanism in producing pyrrole–imidazole alkaloids sceptrin, massadine, and ageliferin. Through de novo synthe...
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| Main Authors: | , , , , , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4205478/ https://ncbi.nlm.nih.gov/pubmed/25301624 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.1255677 |
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