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Comment on Asymmetric Syntheses of Sceptrin and Massadine and Evidence for Biosynthetic Enantiodivergence

Ma, et al. (Reports, 10 October 2014, p. 219) report asymmetric syntheses of Sceptrin and Massadine and through a stereochemical reassignment, claim to “..uncover enantiodivergence as a new biosynthetic paradigm for natural products.” This Technical Comment challenges and clarifies this claim with r...

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Foilsithe in:Science
Main Authors: Sherman, David H., Tsukamoto, Sachiko, Williams, Robert M.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2015
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4499860/
https://ncbi.nlm.nih.gov/pubmed/26160938
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aaa9349
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