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Asymmetric Synthesis of Ageliferin
We describe herein an asymmetric synthesis of ageliferin. A Mn(III)-mediated oxidative radical cyclization reaction was used as the key step to construct the core skeleton of this pyrrole-imidazole dimer. This approach resembles the bio-genic [4+2] dimerization in an intramolecular fashion.
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| 主要な著者: | , , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2011
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| 主題: | |
| オンライン・アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3183238/ https://ncbi.nlm.nih.gov/pubmed/21888421 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja207386q |
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