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Asymmetric Synthesis of Ageliferin

We describe herein an asymmetric synthesis of ageliferin. A Mn(III)-mediated oxidative radical cyclization reaction was used as the key step to construct the core skeleton of this pyrrole-imidazole dimer. This approach resembles the bio-genic [4+2] dimerization in an intramolecular fashion.

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書誌詳細
主要な著者: Wang, Xiao, Ma, Zhiqiang, Lu, Jianming, Tan, Xianghui, Chen, Chuo
フォーマット: Artigo
言語:Inglês
出版事項: 2011
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3183238/
https://ncbi.nlm.nih.gov/pubmed/21888421
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja207386q
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