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Reactions of Indene and Indoles with Platinum Methyl Cations: Indene C-H Activation, Indole π vs. Nitrogen Lone-Pair Coordination
Reactions of indene and various substituted indoles with [(diimine)Pt(II)(Me)(TFE)](+) cations have been studied (diimine = ArN = C(Me) − C(Me) = NAr; TFE = 2,2,2-trifluoroethanol). Indene displaces the TFE ligand from platinum to form a stable π coordination complex that, upon heating, undergoes C-...
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| Publicado no: | Organometallics |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4833004/ https://ncbi.nlm.nih.gov/pubmed/27087735 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om0606643 |
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