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Reactions of Indene and Indoles with Platinum Methyl Cations: Indene C-H Activation, Indole π vs. Nitrogen Lone-Pair Coordination

Reactions of indene and various substituted indoles with [(diimine)Pt(II)(Me)(TFE)](+) cations have been studied (diimine = ArN = C(Me) − C(Me) = NAr; TFE = 2,2,2-trifluoroethanol). Indene displaces the TFE ligand from platinum to form a stable π coordination complex that, upon heating, undergoes C-...

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Bibliografiset tiedot
Julkaisussa:Organometallics
Päätekijät: Williams, Travis J., Labinger, Jay A., Bercaw, John E.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: 2007
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC4833004/
https://ncbi.nlm.nih.gov/pubmed/27087735
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om0606643
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