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Thiophenylazobenzene: An Alternative Photoisomerization Controlled by Lone‐Pair⋅⋅⋅π Interaction

Azoheteroarene photoswitches have attracted attention due to their unique properties. We present the stationary photochromism and ultrafast photoisomerization mechanism of thiophenylazobenzene (TphAB). It demonstrates impressive fatigue resistance and photoisomerization efficiency, and shows favorab...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Slavov, Chavdar, Yang, Chong, Heindl, Andreas H., Wegner, Hermann A., Dreuw, Andreas, Wachtveitl, Josef
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6973119/
https://ncbi.nlm.nih.gov/pubmed/31595575
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201909739
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