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Thiophenylazobenzene: An Alternative Photoisomerization Controlled by Lone‐Pair⋅⋅⋅π Interaction

Azoheteroarene photoswitches have attracted attention due to their unique properties. We present the stationary photochromism and ultrafast photoisomerization mechanism of thiophenylazobenzene (TphAB). It demonstrates impressive fatigue resistance and photoisomerization efficiency, and shows favorab...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Slavov, Chavdar, Yang, Chong, Heindl, Andreas H., Wegner, Hermann A., Dreuw, Andreas, Wachtveitl, Josef
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2019
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6973119/
https://ncbi.nlm.nih.gov/pubmed/31595575
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201909739
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