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Platinum-Catalyzed Terminal-Selective C(sp(3))–H Oxidation of Aliphatic Amines
This paper describes the terminal-selective Pt-catalyzed C(sp(3))–H oxidation of aliphatic amines without the requirement for directing groups. CuCl(2) is employed as a stoichiometric oxidant, and the reactions proceed in high yield at Pt loadings as low as 1 mol %. These transformations are conduct...
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| Published in: | J Am Chem Soc |
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| Main Authors: | , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
2015
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4828934/ https://ncbi.nlm.nih.gov/pubmed/26439251 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b09099 |
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