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High-Potential Electrocatalytic O(2) Reduction with Nitroxyl/NO(x) Mediators: Implications for Fuel Cells and Aerobic Oxidation Catalysis

[Image: see text] Efficient reduction of O(2) to water is a central challenge in energy conversion and many aerobic oxidation reactions. Here, we show that the electrochemical oxygen reduction reaction (ORR) can be achieved at high potentials by using soluble organic nitroxyl and nitrogen oxide (NO(...

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Detalhes bibliográficos
Publicado no:ACS Cent Sci
Main Authors: Gerken, James B., Stahl, Shannon S.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2015
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4827547/
https://ncbi.nlm.nih.gov/pubmed/27162977
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscentsci.5b00163
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