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Mechanism of Alcohol Oxidation Mediated by Copper(II) and Nitroxyl Radicals

[Image: see text] 2,2′-Bipyridine-ligated copper complexes, in combination with TEMPO (2,2,6,6-tetramethylpiperidine-N-oxyl), are highly effective catalysts for aerobic alcohol oxidation. Considerable uncertainty and debate exist over the mechanism of alcohol oxidation mediated by Cu(II) and TEMPO....

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Ryland, Bradford L., McCann, Scott D., Brunold, Thomas C., Stahl, Shannon S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4354946/
https://ncbi.nlm.nih.gov/pubmed/25090238
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja5070137
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