Kinetic Isotope Effect Provides Insight into the Vibrational Relaxation Mechanism of Aromatic Molecules: Application to Cyano-phenylalanine

Varying the reduced mass of an oscillator via isotopic substitution provides a convenient means to alter its vibrational frequency and hence has found wide applications. Herein, we show that this method can also help delineate the vibrational relaxation mechanism, using four isotopomers of the unnat...

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Veröffentlicht in:J Phys Chem Lett
Hauptverfasser: Rodgers, Jeffrey M., Zhang, Wenkai, Bazewicz, Christopher G., Chen, Jianxin, Brewer, Scott H., Gai, Feng
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2016
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4824650/
https://ncbi.nlm.nih.gov/pubmed/26990401
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpclett.6b00325
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