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A Simple Method for Enhancing the Bioorthogonality of Cyclooctyne Reagent

The cross-reactivity between some cyclooctynes and thiols limits the bioorthogonality of the strain-promoted azide–alkyne cycloaddition reaction. We show that a low concentration of β-mercaptoethanol significantly reduces the undesirable side reaction between bicyclononyne (BCN) and cysteine and whi...

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Bibliografiske detaljer
Udgivet i:Chem Commun (Camb)
Main Authors: Tian, He, Sakmar, Thomas P., Huber, Thomas
Format: Artigo
Sprog:Inglês
Udgivet: 2016
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4824645/
https://ncbi.nlm.nih.gov/pubmed/27009873
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6cc01321j
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