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Diastereoselective, Zinc-Catalyzed Alkynylation of α-Bromo Oxocarbenium Ions
We have developed a bromination/alkynylation sequence that enables efficient transformation of simple cyclic enol ethers to difunctionalized products. The success of this strategy relies on a highly diastereselective, zinc-catalyzed addition of terminal alkynes to α-bromo oxocarbenium ions, formed i...
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| Pubblicato in: | Org Lett |
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| Autori principali: | , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2015
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4820761/ https://ncbi.nlm.nih.gov/pubmed/26196257 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.5b01838 |
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