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Diastereoselective, Zinc-Catalyzed Alkynylation of α-Bromo Oxocarbenium Ions
We have developed a bromination/alkynylation sequence that enables efficient transformation of simple cyclic enol ethers to difunctionalized products. The success of this strategy relies on a highly diastereselective, zinc-catalyzed addition of terminal alkynes to α-bromo oxocarbenium ions, formed i...
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| Publicat a: | Org Lett |
|---|---|
| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2015
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4820761/ https://ncbi.nlm.nih.gov/pubmed/26196257 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.5b01838 |
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