Lataa...

Enantioselective, Copper(I)-Catalyzed Alkynylation of Oxocarbenium Ions to Set Diaryl Tetrasubstituted Stereocenters()

We have developed an enantioselective, copper(I)-catalyzed addition of terminal alkynes to isochroman ketals to set diaryl, tetrasubstituted stereocenters. The success of this reaction relies on identification of a Cu/PyBox catalyst capable of distinguishing the faces of the diaryl-substituted oxoca...

Täydet tiedot

Tallennettuna:
Bibliografiset tiedot
Julkaisussa:Angew Chem Int Ed Engl
Päätekijät: Dasgupta, Srimoyee, Rivas, Thomas, Watson, Mary P.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: 2015
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC4819992/
https://ncbi.nlm.nih.gov/pubmed/26403641
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201507373
Tagit: Lisää tagi
Ei tageja, Lisää ensimmäinen tagi!