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Enantioselective, Copper(I)-Catalyzed Alkynylation of Oxocarbenium Ions to Set Diaryl Tetrasubstituted Stereocenters()
We have developed an enantioselective, copper(I)-catalyzed addition of terminal alkynes to isochroman ketals to set diaryl, tetrasubstituted stereocenters. The success of this reaction relies on identification of a Cu/PyBox catalyst capable of distinguishing the faces of the diaryl-substituted oxoca...
Shranjeno v:
| izdano v: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2015
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4819992/ https://ncbi.nlm.nih.gov/pubmed/26403641 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201507373 |
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