The Synthesis, Characterization and Dehydrogenation of Sigma‐Complexes of BN‐Cyclohexanes

The coordination chemistry of the 1,2‐BN‐cyclohexanes 2,2‐R(2)‐1,2‐B,N‐C(4)H(10) (R(2)=HH, MeH, Me(2)) with Ir and Rh metal fragments has been studied. This led to the solution (NMR spectroscopy) and solid‐state (X‐ray diffraction) characterization of [Ir(PCy(3))(2)(H)(2)(η(2)η(2)‐H(2)BNR(2)C(4)H(8)...

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Pubblicato in:Chemistry
Autori principali: Kumar, Amit, Ishibashi, Jacob S. A., Hooper, Thomas N., Mikulas, Tanya C., Dixon, David A., Liu, Shih‐Yuan, Weller, Andrew S.
Natura: Artigo
Lingua:Inglês
Pubblicazione: WILEY‐VCH Verlag 2015
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4818983/
https://ncbi.nlm.nih.gov/pubmed/26602704
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201502986
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