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Thermodynamically Controlled, Dynamic Binding of Diols to a 1,2-BN Cyclohexane Derivative

The reversible covalent binding of diols to an N-Bn 1,2-BN cyclohexane has been studied by (11)B and (1)H NMR spectroscopy and single-crystal X-ray diffraction analysis. The activation barrier for the reversible B–N Lewis acid–base interaction has been measured by variable-temperature NMR with bound...

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Detalhes bibliográficos
Publicado no:Organometallics
Main Authors: Harlow, Gregory P., Zakharov, Lev N., Wu, Gang, Liu, Shih-Yuan
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4364440/
https://ncbi.nlm.nih.gov/pubmed/25798022
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om400697r
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