Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design

Palladium-catalysed C(sp(2))–N cross-coupling (that is, Buchwald–Hartwig amination) is employed widely in synthetic chemistry, including in the pharmaceutical industry, for the synthesis of (hetero)aniline derivatives. However, the cost and relative scarcity of palladium provides motivation for the...

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Veröffentlicht in:Nat Commun
Hauptverfasser: Lavoie, Christopher M., MacQueen, Preston M., Rotta-Loria, Nicolas L., Sawatzky, Ryan S., Borzenko, Andrey, Chisholm, Alicia J., Hargreaves, Breanna K. V., McDonald, Robert, Ferguson, Michael J., Stradiotto, Mark
Format: Artigo
Sprache:Inglês
Veröffentlicht: Nature Publishing Group 2016
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4814586/
https://ncbi.nlm.nih.gov/pubmed/27004442
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms11073
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