An Efficient Protocol for the Palladium-catalyzed Asymmetric Decarboxylative Allylic Alkylation Using Low Palladium Concentrations and a Palladium(II) Precatalyst

Enantioselective catalytic allylic alkylation for the synthesis of 2-alkyl-2-allylcycloalkanones and 3,3-disubstituted pyrrolidinones, piperidinones and piperazinones has been previously reported by our laboratory. The efficient construction of chiral all-carbon quaternary centers by allylic alkylat...

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Publicado en:Adv Synth Catal
Autores principales: Marziale, Alexander N., Duquette, Douglas C., Craig, Robert A., Kim, Kelly E., Liniger, Marc, Numajiri, Yoshitaka, Stoltz, Brian M.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2015
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Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC4811629/
https://ncbi.nlm.nih.gov/pubmed/27042171
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201500253
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