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Palladium-catalyzed decarboxylative allylic alkylation of diastereomeric β-ketoesters

The palladium-catalyzed decarboxylative allylic alkylation of diastereomeric β-ketoesters derived from 4-tert-butylcyclohexanone is described. These experiments were performed to elucidate our understanding of stereoablative enantioconvergent catalysis. A detailed analysis of the product distributio...

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Autori principali: Ma, Sandy, Reeves, Corey M., Craig, Robert A., Stoltz, Brian M.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2014
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4078409/
https://ncbi.nlm.nih.gov/pubmed/24999286
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2014.03.042
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