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Intramolecular Redox-Mannich Reactions: Facile Access to the Tetrahydroprotoberberine Core
Cyclic amines such as pyrrolidine undergo redox-annulations with 2-formylaryl malonates. Concurrent oxidative amine α-C–H bond functionalization and reductive N-alkylation render this transformation redox-neutral. This redox-Mannich process provides regioisomers of classic Reinhoudt reaction product...
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| Publicado no: | Chemistry |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4808586/ https://ncbi.nlm.nih.gov/pubmed/26220197 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201501667 |
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