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Selective Functionalization of Tetrathiafulvalene Using Mg- and Zn-TMP-Bases: Preparation of Mono-, Di-, Tri-, and Tetrasubstituted Derivatives

[Image: see text] The tetrathiafulvalene-scaffold (TTF) reacts selectively in allylation, acylation, arylation, halogenation, and thiolation reactions via magnesium or zinc derivatives that are obtained by a direct metalation with Mg- and Zn-TMP-bases (TMP = 2,2,6,6-tetramethylpiperidyl). This stepw...

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Publicat a:Org Lett
Autors principals: Nafe, Julia, Auras, Florian, Karaghiosoff, Konstantin, Bein, Thomas, Knochel, Paul
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2015
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4797621/
https://ncbi.nlm.nih.gov/pubmed/26469280
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.5b02715
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