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Stereocontrolled regeneration of olefins from epoxides

Through treatment with NaI and trifluoroacetic anhydride, which presumably forms trifluoroacetyl iodide in situ, epoxides can be converted to olefins. This reaction now has been shown to tolerate remote olefins without loss of their individual stereochemistry. A reaction sequence involving regiospec...

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Bibliografske podrobnosti
izdano v:Tetrahedron Lett
Main Authors: Wills, Veronica S., Zhou, Xiang, Allen, Cheryl, Holstein, Sarah A., Wiemer, David F.
Format: Artigo
Jezik:Inglês
Izdano: 2016
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4778745/
https://ncbi.nlm.nih.gov/pubmed/26955189
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2016.02.041
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