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Solvent-Dependent Pyranopterin Cyclization in Molybdenum Cofactor Model Complexes
The conserved pterin dithiolene ligand that coordinates molybdenum (Mo) in the cofactor (Moco) of mononuclear Mo enzymes can exist in both a tricyclic pyranopterin dithiolene form and as a bicyclic pterin-dithiolene form as observed in protein crystal structures of several bacterial molybdoenzymes....
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| Publicado en: | Inorg Chem |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2015
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4752123/ https://ncbi.nlm.nih.gov/pubmed/25942001 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.5b00532 |
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