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Implications of Pyran Cyclization and Pterin Conformation on Oxidized Forms of the Molybdenum Cofactor
The large family of mononuclear molybdenum and tungsten enzymes all possess the special ligand molybdopterin (MPT), which consists of a metal-binding dithiolene chelate covalently bound to a pyranopterin group. MPT pyran cyclization/scission processes have been proposed to modulate the reactivity of...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6542470/ https://ncbi.nlm.nih.gov/pubmed/30200760 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b05777 |
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