Implications of Pyran Cyclization and Pterin Conformation on Oxidized Forms of the Molybdenum Cofactor

The large family of mononuclear molybdenum and tungsten enzymes all possess the special ligand molybdopterin (MPT), which consists of a metal-binding dithiolene chelate covalently bound to a pyranopterin group. MPT pyran cyclization/scission processes have been proposed to modulate the reactivity of...

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Bibliographic Details
Published in:J Am Chem Soc
Main Authors: Gisewhite, Douglas R., Yang, Jing, Williams, Benjamin R., Esmail, Alisha, Stein, Benjamin, Kirk, Martin L., Burgmayer, Sharon J. N.
Format: Artigo
Language:Inglês
Published: 2018
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6542470/
https://ncbi.nlm.nih.gov/pubmed/30200760
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b05777
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