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Selective Aromatic C–H Hydroxylation Enabled by η(6)-Coordination to Iridium(III)
We report an aromatic C–H hydroxylation protocol in which the arene is activated through η(6)-coordination to an iridium(III) complex. η(6)-Coordination of the arene increases its electrophilicity and allows for high positional selectivity of hydroxylation at the site of least electron density. Thro...
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| Pubblicato in: | Organometallics |
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| Autori principali: | , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2015
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4750501/ https://ncbi.nlm.nih.gov/pubmed/26877574 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.5b00731 |
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