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Crystal structure of the pristine peroxidase ferryl center and its relevance to proton-coupled electron transfer
The reaction of peroxides with peroxidases oxidizes the heme iron from Fe(III) to Fe(IV)=O and a porphyrin or aromatic side chain to a cationic radical. X-ray–generated hydrated electrons rapidly reduce Fe(IV), thereby requiring very short exposures using many crystals, and, even then, some reductio...
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| Publicado no: | Proc Natl Acad Sci U S A |
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| Main Authors: | , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4747753/ https://ncbi.nlm.nih.gov/pubmed/26787871 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1521664113 |
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