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Crystallographic and Single Crystal Spectral Analysis of the Peroxidase Ferryl Intermediate

The ferryl (Fe(IV)O) intermediate is important in many heme enzymes and thus the precise nature of the Fe(IV)-O bond is critical in understanding enzymatic mechanisms. The 1.40 Å crystal structure of cytochrome c peroxidase Compound I has been solved as a function of x-ray dose while monitoring the...

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Detalhes bibliográficos
Main Authors: Meharenn, Yergalem T., Doukov, Tzanko, Li, Huiying, Soltis, S. Michael, Poulos, Thomas L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3202969/
https://ncbi.nlm.nih.gov/pubmed/20230048
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi100238r
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