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Selective Photodissociation of Acetonitrile Ligands in Ruthenium Polypyridyl Complexes Studied by Density Functional Theory

Metal complexes that release ligands upon photoexcitation are important tools for biological research and show great potential as highly specific therapeutics. Upon excitation with visible light, [Ru(TQA)(MeCN)(2)](2+) [TQA = tris(2-quinolinylmethyl)amine] exchanges one of the two acetonitriles (MeC...

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Publicat a:Inorg Chem
Autors principals: Tu, Yi-Jung, Mazumder, Shivnath, Endicott, John F., Turro, Claudia, Kodanko, Jeremy J., Schlegel, H. Bernhard
Format: Artigo
Idioma:Inglês
Publicat: 2015
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4743049/
https://ncbi.nlm.nih.gov/pubmed/26244447
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.5b01202
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